Molarity is a fundamental concept in chemistry that describes the concentration of a solution. It is calculated as the number of moles of solute per liter of solution. Understanding molarity is essential for various applications in scientific fields, from laboratory experiments to industrial processes. In this post, we will explore ten molarity problems that will help you test your skills and deepen your understanding of this crucial topic. Whether you’re a student preparing for exams or someone who wants to refresh their chemistry knowledge, these problems will provide you with valuable practice. Let’s dive in! 🌊
What is Molarity?
Molarity (M) is defined by the equation:
Molarity (M) = Moles of solute / Liters of solution
In this equation:
- Moles of solute is the amount of solute (the substance being dissolved) present in the solution.
- Liters of solution is the total volume of the solution.
Understanding how to manipulate this formula is key to solving molarity problems effectively.
Molarity Problems
Below are ten molarity problems, complete with solutions and explanations to help you grasp the concept thoroughly.
Problem 1: Calculating Molarity
Question: If 5 grams of sodium chloride (NaCl) are dissolved in enough water to make 0.5 liters of solution, what is the molarity?
Solution:
-
Calculate the moles of NaCl:
- Molar mass of NaCl = 58.44 g/mol
- Moles of NaCl = 5 g / 58.44 g/mol = 0.0855 mol
-
Use the molarity formula:
- Molarity = 0.0855 mol / 0.5 L = 0.171 M
Problem 2: Finding Volume from Molarity
Question: How many liters of a 0.3 M potassium sulfate (K2SO4) solution contain 0.6 moles of K2SO4?
Solution:
-
Rearrange the formula:
- Volume (L) = Moles / Molarity
-
Calculate:
- Volume = 0.6 mol / 0.3 M = 2 L
Problem 3: Dilution Calculations
Question: If you have 1 liter of a 1 M solution of hydrochloric acid (HCl) and you dilute it to a total volume of 3 liters, what is the new molarity?
Solution:
-
Use the dilution formula:
- C1V1 = C2V2
-
Substitute values:
- (1 M)(1 L) = C2(3 L)
-
Solve for C2:
- C2 = 1/3 M = 0.333 M
Problem 4: Mixing Solutions
Question: If you mix 200 mL of a 1.5 M NaOH solution with 300 mL of a 0.5 M NaOH solution, what is the molarity of the resulting solution?
Solution:
-
Calculate moles from each solution:
- Moles from 1.5 M solution = 1.5 mol/L × 0.2 L = 0.3 mol
- Moles from 0.5 M solution = 0.5 mol/L × 0.3 L = 0.15 mol
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Total moles = 0.3 mol + 0.15 mol = 0.45 mol
-
Total volume = 200 mL + 300 mL = 500 mL = 0.5 L
-
Molarity = 0.45 mol / 0.5 L = 0.9 M
Problem 5: Finding Moles
Question: How many moles of solute are present in 250 mL of a 0.4 M calcium chloride (CaCl2) solution?
Solution:
-
Convert volume to liters:
- 250 mL = 0.25 L
-
Calculate moles:
- Moles = Molarity × Volume = 0.4 M × 0.25 L = 0.1 mol
Problem 6: Molarity of a Saturated Solution
Question: A saturated solution of sugar (C12H22O11) at room temperature contains 200 grams of sugar in 1 liter of water. What is the molarity?
Solution:
-
Calculate moles of sugar:
- Molar mass of sugar = 342.3 g/mol
- Moles of sugar = 200 g / 342.3 g/mol = 0.584 mol
-
Calculate molarity:
- Molarity = 0.584 mol / 1 L = 0.584 M
Problem 7: Concentrating a Solution
Question: If 4 liters of a 0.5 M acetic acid (CH3COOH) solution are evaporated until the volume is reduced to 2 liters, what is the new molarity?
Solution:
-
Calculate initial moles:
- Moles = 0.5 M × 4 L = 2 mol
-
Molarity after evaporation:
- Molarity = 2 mol / 2 L = 1 M
Problem 8: Serial Dilution
Question: You take 10 mL of a 2 M solution of nitric acid (HNO3) and dilute it to 50 mL. What is the molarity of the diluted solution?
Solution:
-
Use dilution formula:
- C1V1 = C2V2
- (2 M)(10 mL) = C2(50 mL)
-
Solve for C2:
- C2 = (2 M × 10 mL) / 50 mL = 0.4 M
Problem 9: Buret Titration
Question: If it takes 25 mL of a 0.2 M sodium hydroxide (NaOH) solution to completely neutralize 50 mL of hydrochloric acid (HCl), what is the molarity of the HCl solution?
Solution:
-
Calculate moles of NaOH:
- Moles = 0.2 M × 0.025 L = 0.005 mol
-
Since the reaction is 1:1, moles of HCl = 0.005 mol
-
Calculate molarity of HCl:
- Molarity = Moles / Volume (in L) = 0.005 mol / 0.050 L = 0.1 M
Problem 10: Preparing a Solution
Question: How would you prepare 500 mL of a 0.75 M sodium bicarbonate (NaHCO3) solution?
Solution:
-
Calculate the moles needed:
- Moles = Molarity × Volume = 0.75 M × 0.5 L = 0.375 mol
-
Calculate the mass of NaHCO3 required:
- Molar mass = 84.01 g/mol
- Mass = 0.375 mol × 84.01 g/mol = 31.5 g
-
Dissolve 31.5 grams of NaHCO3 in enough water to make a total volume of 500 mL.
Troubleshooting Common Mistakes
Understanding molarity can be tricky, and there are common pitfalls to watch out for. Here are some helpful tips for avoiding mistakes:
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Mixing up Moles and Molarity: Always remember that molarity is based on the volume of the entire solution, not just the solute. Ensure you're using the correct figures.
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Volume Units: Make sure to convert your volume to liters when calculating molarity, as it is expressed in moles per liter.
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Dilution Confusion: When diluting a solution, remember that the moles of solute remain constant before and after dilution, making it easier to calculate the new concentration.
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Using Accurate Measurements: Always use precise measuring tools to ensure accurate volume measurements, as small errors can lead to significant discrepancies in your calculations.
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Recheck Calculations: It's easy to make arithmetic errors. Double-check your calculations, especially when dealing with fractions and large numbers.
<div class="faq-section"> <div class="faq-container"> <h2>Frequently Asked Questions</h2> <div class="faq-item"> <div class="faq-question"> <h3>What is the difference between molarity and molality?</h3> <span class="faq-toggle">+</span> </div> <div class="faq-answer"> <p>Molarity is the concentration of a solution expressed as moles of solute per liter of solution, while molality is expressed as moles of solute per kilogram of solvent.</p> </div> </div> <div class="faq-item"> <div class="faq-question"> <h3>How do you convert molarity to mass concentration?</h3> <span class="faq-toggle">+</span> </div> <div class="faq-answer"> <p>Multiply the molarity by the molar mass of the solute to obtain the mass concentration in grams per liter.</p> </div> </div> <div class="faq-item"> <div class="faq-question"> <h3>Can molarity be negative?</h3> <span class="faq-toggle">+</span> </div> <div class="faq-answer"> <p>No, molarity cannot be negative as it represents a concentration; a negative value would not have any physical meaning in chemistry.</p> </div> </div> </div> </div>
In summary, mastering molarity requires practice and a good understanding of the calculations involved. These ten problems provide a comprehensive overview of various scenarios you might encounter in your studies or professional work. Be sure to work through these problems and explore related tutorials to solidify your grasp of molarity.
<p class="pro-note">💡Pro Tip: Practice regularly and apply what you've learned to real-world scenarios to enhance your understanding of molarity!</p>